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Subject - Chemistry:

Basics

MCQ - 175-2361

Question:

Synthetic rubber is made by polymerization of

  1. chloroform
  2. Acetylene
  3. Divinyl a cetylene
  4. Acetylene

Correct Answer: B

Explanation:

Chloroprene is the common name for the organic compound 2-chlorobuta-1,3-diene, which has the formula CH2=CCl-CH=CH2. This colorless liquid is the monomer for the production of the polymerpolychloroprene, a type of synthetic rubber. Polychloroprene is better known to the public as Neoprene.
Chloroprene production was dominated by the "acetylene process," which was modeled after the original synthesis of vinylacetylene. In this process, acetylene is dimerized to give vinyl acetylene, which is then combined with hydrogen chloride to afford 4-chloro-1,2-butadiene (an allene derivative), which in the presence of cuprous chloride, rearranges to the targeted 2-chlorobuta-1,3-diene:

HC≡C-CH=CH2 + HCl → H2C=CCl-CH=CH2

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