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Subject - Chemistry:

Basics

MCQ - 71-2257

Question:

Which one of the following reagents will distinguish between benzaldehyde, C6H5CHO, and phenylethanone, C6H5COCH3?

  1. Aqueous bromine
  2. Aqueous diamminesilver (I) ions
  3. 2,4-dinitrophenylhydrazine
  4. Aqueous diamminesilver (I) ions

Correct Answer: B

Explanation:

C6H5CHO, being an aldehyde, reduces [Ag(NH3)2]+ (Tollen’s reagent) to give a silver mirror but C6H5COCH3being a ketone, is unable to.

C6H5CHO + 2[Ag(NH3)2]++ 3OH-

C6H5CO2- +2Ag + 4NH3 + 2H2O

Record Performance

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